Stereoselective cathodic synthesis of 8-substituted (1R,3R,4S)-menthylamines-Reference-Cited by-同舟云学术

Stereoselective cathodic synthesis of 8-substituted (1R,3R,4S)-menthylamines

Published:2015-02-27 Issue: Volume:11 Page:294-301
ISSN:1860-5397
Container-title:Beilstein Journal of Organic Chemistry
language:en
Short-container-title:Beilstein J. Org. Chem.

Author:

Edinger Carolin,Kulisch Jörn,Waldvogel Siegfried R

Abstract

The electrochemical generation of menthylamines from the corresponding menthone oximes equipped with an additional substituent in position 8 is described. Due to 1,3-diaxial interactions a pronounced diastereoselectivity for the menthylamines is found.

Publisher

Beilstein Institut

Subject

Organic Chemistry

Link

https://www.beilstein-journals.org/bjoc/content/pdf/1860-5397-11-34.pdf

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