Diametric calix[6]arene-based phosphine gold(I) cavitands-Reference-Cited by-同舟云学术

Diametric calix[6]arene-based phosphine gold(I) cavitands

Published:2022-02-10 Issue: Volume:18 Page:190-196
ISSN:1860-5397
Container-title:Beilstein Journal of Organic Chemistry
language:en
Short-container-title:Beilstein J. Org. Chem.

Author:

Giovanardi Gabriele,Secchi Andrea^ORCID,Arduini Arturo,Cera Gianpiero^ORCID

Abstract

We report the synthesis and characterization, in low polarity solvents, of a novel class of diametric phosphine gold(I) cavitands characterized by a 1,2,3-alternate geometry. Preliminary catalytic studies were performed on a model cycloisomerization of 1,6-enynes as a function of the relative orientation of the bonded gold(I) nuclei with respect to the macrocyclic cavity.

Publisher

Beilstein Institut

Subject

Organic Chemistry

Link

https://www.beilstein-journals.org/bjoc/content/pdf/1860-5397-18-21.pdf

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