Visible light-mediated difluoroalkylation of electron-deficient alkenes-Reference-Cited by-同舟云学术

Visible light-mediated difluoroalkylation of electron-deficient alkenes

Published:2018-07-02 Issue: Volume:14 Page:1637-1641
ISSN:1860-5397
Container-title:Beilstein Journal of Organic Chemistry
language:en
Short-container-title:Beilstein J. Org. Chem.

Author:

Supranovich Vyacheslav I,Levin Vitalij V,Struchkova Marina I,Hu Jinbo,Dilman Alexander D^ORCID

Abstract

A method for the reductive difluoroalkylation of electron-deficient alkenes using 1,1-difluorinated iodides mediated by irradiation with blue light is described. The reaction involves radical addition of 1,1-difluorinated radicals at the double bond followed by hydrogen atom transfer from sodium cyanoborohydride.

Publisher

Beilstein Institut

Subject

Organic Chemistry

Link

https://www.beilstein-journals.org/bjoc/content/pdf/1860-5397-14-139.pdf

Reference52 articles.

1. Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)

2. Fluorine in medicinal chemistry

3. Introduction of Fluorine and Fluorine-Containing Functional Groups

4. Recent Progress toward the Introduction of Functionalized Difluoromethylated Building Blocks onto C(sp2) and C(sp) Centers

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