A side-on Mn(iii)–peroxo supported by a non-heme pentadentate N3Py2 ligand: synthesis, characterization and reactivity studies-Reference-Cited by-同舟云学术

A side-on Mn(iii)–peroxo supported by a non-heme pentadentate N3Py2 ligand: synthesis, characterization and reactivity studies

Published:2021 Issue:8 Volume:50 Page:2824-2831
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Narulkar Dattaprasad D.¹²³⁴,Ansari Azaj⁵^ORCID,Vardhaman Anil Kumar⁶^ORCID,Harmalkar Sarvesh S.¹²³,Lingamallu Giribabu⁶^ORCID,Dhavale Vishal M.⁷^ORCID,Sankaralingam Muniyandi⁸^ORCID,Das Sandip⁹^ORCID,Kumar Pankaj⁹^ORCID,Dhuri Sunder N.¹²³^ORCID

Affiliation:

1. School of Chemical Sciences

2. Goa University

3. India

4. Department of Chemistry, Dnyanprassarak Mandal’s College and Research Centre, Assagao, Goa-403507, India

5. Department of Chemistry, Central University of Haryana, Mahendergarh-123031, Haryana, India

6. Polymers & Functional Materials Division, CSIR-Indian Institute of Chemical Technology, Uppal Road, Tarnaka, Hyderabad-500007, India

7. CSIR-Central Electrochemical Research Institute, CSIR Madras Complex, Taramani, Chennai-600 113, India

8. Bioinspired & Biomimetic Inorganic Chemistry Lab, Department of Chemistry, National Institute of Technology Calicut, Kozhikode, Kerala 673601, India

9. Indian Institute of Science Education and Research (IISER), Tirupati-517507, India

Abstract

A new non-heme Mn(iii)–peroxo (1a) has been generated, characterized and reactivity is in aldehyde deformylation reaction. A nucleophilic reactivity of 1a in aldehyde oxidation is proposed.

Funder

Council of Scientific and Industrial Research, India

University Grants Commission

Department of Science and Technology, Ministry of Science and Technology, India

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT03706K

Reference71 articles.

1. P. R. O. De Montellano , Cytochrome P450: structure, mechanism, and biochemistry , Springer Science & Business Media , 2005

2. J. Lawrence Que , W. B.Tolman , J.McCleverty and T. J.Meyer , in Comprehensive Coordination Chemistry II: From Biology to Nanotechnology , Elsevier , Oxford , 2004

3. B. Meunier , Biomimetic oxidations catalyzed by transition metal complexes , World Scientific , 2000

4. E. J. Larson and V. J.Pecoraro , Manganese redox enzymes , VCH Publishers , New York , 1992

5. Kinetic studies of superoxide dismutases: properties of the manganese-containing protein from Thermus thermophilus

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