Spectroluminescence measurements of the stability constants of CanUO2(CO3)3(4−2n)− complexes in NaClO4 medium and the investigation of interaction effects-Reference-Cited by-同舟云学术

Spectroluminescence measurements of the stability constants of CanUO2(CO3)3(4−2n)− complexes in NaClO4 medium and the investigation of interaction effects

Published:2020 Issue:43 Volume:49 Page:15443-15460
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Shang Chengming¹²³⁴⁵,Reiller Pascal E.¹²³⁴⁵^ORCID,Vercouter Thomas¹²³⁴⁵^ORCID

Affiliation:

1. Université Paris-Saclay

2. CEA

3. Service d’Études Analytiques et de Réactivité des Surfaces (SEARS)

4. F-91191 Gif-sur-Yvette CEDEX

5. France

Abstract

The stability constants of ternary calcium uranyl tricarbonate complexes, CaUO₂(CO₃)₃²⁻ and Ca₂UO₂(CO₃)₃(aq), were determined in NaClO₄ medium at various ionic strengths using time-resolved laser-induced luminescence spectroscopy (TRLS).

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT03164J

Reference87 articles.

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4. Mixed complexes of alkaline earth uranyl carbonates: A laser-induced time-resolved fluorescence spectroscopic study

5. The influence of the temperature on the carbonate complexation of uranium(VI): a spectroscopic study

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