Development of a novel scorpionate ligand with 6-methylpyridine and comparison of the structural and electronic properties of nickel(<scp>ii</scp>) complexes with related tris(azolyl)borates-Reference-Cited by-同舟云学术

Development of a novel scorpionate ligand with 6-methylpyridine and comparison of the structural and electronic properties of nickel(ii) complexes with related tris(azolyl)borates

Published:2022 Issue:27 Volume:51 Page:10338-10342
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Fujiwara Yusuke¹,Takayama Tomoaki¹,Nakazawa Jun¹^ORCID,Okamura Masaya¹^ORCID,Hikichi Shiro¹^ORCID

Affiliation:

1. Department of Material and Life Chemistry, Faculty of Engineering, Kanagawa University, Yokohama 221-8686, Japan

Abstract

A facially-capping tris(6-methylpyridyl)phenylborate is highly electron-donating and its nickel complex is potent mCPBA activator.

Funder

Kanagawa University

Core Research for Evolutional Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01548J

Reference34 articles.

1. S.Trofimenko , Scorpionates – The Coordination Chemistry of Polypyrazolylborate Ligands , Imperial College Press , London , 1999

2. C.Pettinari , Scorpionates II: Chelating Borate Ligans , Imperial College Press , London , 2008

3. Electronic Structure of Four-Coordinate C3v Nickel(II) Scorpionate Complexes: Investigation by High-Frequency and -Field Electron Paramagnetic Resonance and Electronic Absorption Spectroscopies

4. A New Scorpionate Ligand: Tris(4,4-dimethyl-2-oxazolinyl)borate and Its Zirconium(IV) Complexes

5. Bis(oxazolinyl)phenylborane: A Lewis acid-containing ligand for methide abstraction-based coordination to aluminum(III)

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