Introduction of axial chirality at a spiro carbon atom in the synthesis of pentaerythritol–imine macrocycles-Reference-Cited by-同舟云学术

Introduction of axial chirality at a spiro carbon atom in the synthesis of pentaerythritol–imine macrocycles

Published:2018 Issue:6 Volume:16 Page:981-987
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Grajewski J.¹²³⁴^ORCID,Piotrowska K.¹²³⁴^ORCID,Zgorzelak M.¹²³⁴,Janiak A.¹²³⁴^ORCID,Biniek-Antosiak K.¹²³⁴,Rychlewska U.¹²³⁴^ORCID,Gawronski J.¹²³⁴^ORCID

Affiliation:

1. Adam Mickiewicz University

2. Department of Chemistry

3. 61-614 Poznań

4. Poland

Abstract

The synthesis of novel doubly chiral macrocycles with spiro carbon atoms of defined chirality proceeds by either the freezing of a labile spiro-diboronate moiety or the diastereomeric fitting of a rigid spiro-acetal fragment.

Funder

Narodowe Centrum Nauki

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/OB/C7OB02672B

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