Highly chemoselective hydrogenation of cyclic imides to ω-hydroxylactams or ω-hydroxyamides catalyzed by iridium catalysts

Author:

Wu Chao12,Wang Jiang2,Zhang Xumu2ORCID,Zhang Runtong2,Ma Baode2ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, People's Republic of China

2. Department of Chemistry, Southern University of Science and Technology, Shenzhen 518000, People's Republic of China

Abstract

Several novel ferrocene-based PNN ligands were prepared, which were found to be highly effective catalysts (TON up to 50 000) for the homogeneous hydrogenation of cyclic imides with iridium.

Funder

National Natural Science Foundation of China

Science, Technology and Innovation Commission of Shenzhen Municipality

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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