Structural relations in (1 : 1) and (2 : 1) cyanobenzene-ethylenedithio-TTF radical salts; the role of CN⋯H interactions

Author:

Lopes Gonçalo12345,Gama Vasco12345ORCID,Simão Dulce62375ORCID,Santos Isabel C.12345ORCID,Lopes Elsa B.12345ORCID,Pereira Laura C. J.12345ORCID,Almeida Manuel12345ORCID,Rabaça Sandra12345ORCID

Affiliation:

1. C2TN, Centro de Ciências e Tecnologias Nucleares

2. Instituto Superior Técnico

3. Universidade de Lisboa

4. 2695-066 Bobadela LRS

5. Portugal

6. Centro de Química Estrutural

7. P-1049-001 Lisboa

Abstract

Radical cation salts of 4-CNB-EDT-TTF presenting CN⋯H pairing interactions, semiconducting properties and chains of antiferromagnetically coupled donor dimers.

Funder

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Reference31 articles.

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2. A. Nangia , in Organic Crystal Engineering: Frontiers in Crystal Engineering , ed. E. R. T. Tiekink , J. Vittal and M. Zaworotko , John Wiley & Sons , Chichester , 2010 , ch. 5, pp. 151–189

3. Hydrogen Bonded Supramolecular Structures , ed. Z.-T. Li and L.-Z. Wu , Springer , Berlin-Heidelberg , 2015

4. Activation of Hydrogen- and Halogen-Bonding Interactions in Tetrathiafulvalene-Based Crystalline Molecular Conductors

5. Cooperation of Hydrogen-Bond and Charge-Transfer Interactions in Molecular Complexes in the Solid State

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