Synthesis of spirocyclic heterocycles from α,β-unsaturated N-acyliminium ions-Reference-Cited by-同舟云学术

Synthesis of spirocyclic heterocycles from α,β-unsaturated N-acyliminium ions

Published:2021 Issue:1 Volume:19 Page:259-272
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Thaima Thanphat¹²³⁴^ORCID,Yazici Arife¹²³⁴,Auranwiwat Chiramet¹²³⁴⁵^ORCID,Willis Anthony C.⁶⁷⁸⁴^ORCID,Wille Uta⁹¹⁰¹¹¹²⁴^ORCID,Limtharakul Thunwadee⁵¹³¹⁴¹⁵¹⁶^ORCID,Pyne Stephen. G.¹²³⁴^ORCID

Affiliation:

1. School of Chemistry and Molecular Bioscience

2. University of Wollongong

3. Wollongong

4. Australia

5. Department of Chemistry

6. Research School of Chemistry

7. Australian National University

8. Canberra

9. School of Chemistry

10. Bio21 Institute

11. University of Melbourne

12. Parkville

13. Faculty of Science

14. and the Research Center on Chemistry for Development of Health Promoting Products from Northern Resources

15. Chiang Mai University

16. Chiang Mai 50200

Abstract

The reactions of α,β-unsaturated N-acyliminium ions, generated in situ from 4(S)-O-substitutedhydroxy-5-hydroxy-5-vinyl-N-alkylpyrrolidin-2-ones, with allylsilanes and indoles leading to the formation of spirocyclic heterocycles, are reported.

Funder

Australian Research Council

University of Wollongong

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/OB/D0OB02075C

Reference20 articles.

1. Intramolecular reactions of N-acyliminium intermediates

2. New Developments in the Chemistry of N-Acyliminium Ions and Related Intermediates

3. Cyclizations of N-Acyliminium Ions

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