Combined theoretical and time-resolved photoluminescence investigations of [Mo6Bri8Bra6]2− metal cluster units: evidence of dual emission-Reference-Cited by-同舟云学术

Combined theoretical and time-resolved photoluminescence investigations of [Mo6Bri8Bra6]2− metal cluster units: evidence of dual emission

Published:2015 Issue:43 Volume:17 Page:28574-28585
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Costuas K.¹²³,Garreau A.⁴⁵⁶³,Bulou A.⁷⁸⁶³,Fontaine B.¹²³,Cuny J.¹²³⁹¹⁰,Gautier R.¹²³,Mortier M.¹¹¹²⁶¹³³,Molard Y.¹²³,Duvail J.-L.⁴⁵⁶³,Faulques E.⁴⁵⁶³,Cordier S.¹²³

Affiliation:

1. Institut des Sciences Chimiques de Rennes

2. CNRS - ENSC Rennes - Université de Rennes

3. France

4. Institut des Matériaux Jean Rouxel

5. Université de Nantes

6. CNRS

7. Institut des Molécules et Matériaux du Mans/PEC

8. Université du Maine

9. Laboratoire de Chimie et Physique Quantiques

10. LCPQ/IRSAMC

11. Institut de Recherche de Chimie Paris

12. Chimie ParisTech

13. PSL Research University

Abstract

Distinct emissive species have been identified in [Mo₆Brⁱ₈Br^a₆]²⁻ containing systems. Strong geometrical relaxations of the triplet excited states are responsible for the huge energy shift leading to intense red-NIR emission.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP03960F

Reference77 articles.

1. Novel Nanomaterials Based on Inorganic Molybdenum Octahedral Clusters

2. Inorganic Molybdenum Octahedral Nanosized Cluster Units, Versatile Functional Building Block for Nanoarchitectonics

3. Potential of Chevrel phases for thermoelectric applications

4. Promising thermoelectric properties in AgxMo9Se11 compounds (3.4≤x≤3.9)

Cited by 62 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. The route to Re6Te8 cluster complexes with organic ligands;Polyhedron;2024-03

2. Cationic cluster complex [{Mo6I8}(H2O)4(OH)2]2+ with diphenyl phosphate anions: Structure and optical properties behavior;Inorganica Chimica Acta;2024-01

3. Game of Crowns: Na⁺Is Coming! Red NIR-Emissive Hybrid Liquid Crystals Containing Discotic Crown Ethers and Na₂Mo₆X₈ⁱCl₆(Xⁱ= Cl or Br);ACS Applied Materials & Interfaces;2023-08-11

4. The Remarkably Robust, Photoactive Tungsten Iodide Cluster [W₆I₁₂(NCC₆H₅)₂];European Journal of Inorganic Chemistry;2023-05-09

5. Recent developments on luminescent octahedral transition metal cluster complexes towards biological applications;Coordination Chemistry Reviews;2023-04