Uncatalyzed, on water oxygenative cleavage of inert C–N bond with concomitant 8,7-amino shift in 8-aminoquinoline derivatives-Reference-Cited by-同舟云学术

Uncatalyzed, on water oxygenative cleavage of inert C–N bond with concomitant 8,7-amino shift in 8-aminoquinoline derivatives

Published:2019 Issue:7 Volume:21 Page:1735-1742
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Botla Vinayak¹²³⁴,Pilli NavyaSree¹²³⁴⁵,Malapaka Chandrasekharam¹²³⁴⁵^ORCID

Affiliation:

1. P&FM Division

2. CSIR-Indian Institute of Chemical Technology

3. Hyderabad-500007

4. India

5. Academy of Scientific and Innovative Research (AcSIR)

Abstract

Oxygenative cleavage of an inert C_Ar–NH₂ bond with concomitant 1,2 amine migration in 8-aminoquinoline derivatives is achieved through an efficient, catalyst free, one step synthesis of 8-benzyloxy, 7-aminoquinoline directly from 8-aminoquinoline in water at room temperature.

Funder

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/GC/C9GC00289H

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3. Transition-metal catalysed C–N bond activation