Concentration-dependent aggregation of methylene blue acting as a photoredox catalyst

Author:

Thompson Benjamin J.12,Kumar Anshu13,Huxter Vanessa M.13ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, University of Arizona, Tucson, Arizona 85721, USA

2. Department of Optical Sciences, University of Arizona, Tucson, Arizona 85721, USA

3. Department of Physics, University of Arizona, Tucson, Arizona 85721, USA

Abstract

Methylene blue is used as a red-light photoredox catalyst for oxidative hydroxylation reactions. At typical loadings methylene blue forms dimers that do not participate in the reaction limiting the availability of the catalyst.

Funder

American Chemical Society Petroleum Research Fund

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

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