Full optimization of dynamic nuclear polarization on a 1 tesla benchtop polarizer with hyperpolarizing solids

Author:

Vaneeckhaute Ewoud1ORCID,Bocquelet Charlotte1ORCID,Bellier Léa1,Le Huu-Nghia2,Rougier Nathan1,Jegadeesan Shebha Anandhi3ORCID,Vinod-Kumar Sanjay3ORCID,Mathies Guinevere3ORCID,Veyre Laurent2,Thieuleux Chloe2ORCID,Melzi Roberto4,Banks Daniel5ORCID,Kempf James5,Stern Quentin1ORCID,Jannin Sami1ORCID

Affiliation:

1. Université Claude Bernard Lyon 1, CNRS, ENS Lyon, UCBL, CRMN UMR 5082, 69100 Villeurbanne, France

2. Université Claude Bernard Lyon 1, Institut de Chimie de Lyon, CP2M UMR 5128 CNRS-UCBL-CPE Lyon, 69616 Villeurbanne, France

3. Department of Chemistry, University of Konstanz, Universitätsstr. 10, 78464, Konstanz, Germany

4. Bruker Italia S.r.l., Viale V. Lancetti 43, 20158 Milano, Italy

5. Bruker Biospin, Billerica, Massachusetts 01821, USA

Abstract

In a benchtop DNP polarizer operating at 1 T and 77 K, signal enhancements up to 100 generated in less than a second are reported for nitroxide radicals optimized in terms of concentration both in solvated and immobilized form.

Funder

European Research Council

Agence Nationale de la Recherche

Centre National de la Recherche Scientifique

Université Claude Bernard Lyon 1

École Normale Supérieure de Lyon

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

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