Imidazoline synthesis: mechanistic investigations show that Fe catalysts promote a new multicomponent redox reaction-Reference-Cited by-同舟云学术

Imidazoline synthesis: mechanistic investigations show that Fe catalysts promote a new multicomponent redox reaction

Published:2021 Issue:19 Volume:50 Page:6512-6519
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Coin Guillaume¹²³⁴⁵,Dubourdeaux Patrick¹²³⁴⁵,Bayle Pierre-Alain¹²⁶⁷⁵,Lebrun Colette¹²³⁸⁵,Maldivi Pascale¹²³⁸⁵,Latour Jean-Marc¹²³⁴⁵^ORCID

Affiliation:

1. Univ. Grenoble Alpes

2. CEA

3. CNRS

4. IRIG – LCBM/pmb

5. F-38000 Grenoble

6. IRIG

7. MEM

8. IRIG – SyMMES

Abstract

Integrated experimental and computational studies reveal a new mechanism for Fe-catalyzed imidazoline synthesis through combined nitrene transfer and acetonitrile attack of a styrenyl radical intermediate.

Funder

Agence Nationale de la Recherche

Grand Équipement National De Calcul Intensif

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00919B

Reference41 articles.

1. Biologically active compounds based on the privileged 2-imidazoline scaffold: The world beyond adrenergic/imidazoline receptor modulators

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3. Significance of the imidazoline receptors in toxicology

4. Imidazoline scaffold in medicinal chemistry: a patent review (2012–2015)

5. Development of Imidazoline-2-Thiones Based Two-Photon Fluorescence Probes for Imaging Hypochlorite Generation in a Co-Culture System

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