Assignment of photoelectron spectra of silatranes: first ionization energies and the nature of the dative Si←N contact
Author:
Affiliation:
1. A. E. Favorsky Irkutsk Institute of Chemistry
2. Siberian Branch of the Russian Academy of Sciences Favorsky
3. Irkutsk 664033
4. Russian Federation
Abstract
The problematic experimental (8–12 eV) photoelectron spectra of silatranes were theoretically studied and the correlation was found between the first vertical ionization energies, VIEs1, and the various characteristics of the coordination Si←N contact.
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP04341G
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