Investigating subtle 4f vs. 5f coordination differences using kinetically inert Eu(iii), Tb(iii), and Cm(iii) complexes of a coumarin-appended 1,4,7,10-tetraazacyclododecane-1,4,7-triacetate (DO3A) ligand-Reference-Cited by-同舟云学术

Investigating subtle 4f vs. 5f coordination differences using kinetically inert Eu(iii), Tb(iii), and Cm(iii) complexes of a coumarin-appended 1,4,7,10-tetraazacyclododecane-1,4,7-triacetate (DO3A) ligand

Published:2018 Issue:21 Volume:47 Page:7362-7369
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Junker Anne Kathrine R.¹²³⁴,Deblonde Gauthier J.-P.⁵⁶⁷⁸^ORCID,Abergel Rebecca J.⁵⁶⁷⁸⁹^ORCID,Sørensen Thomas Just¹²³⁴^ORCID

Affiliation:

1. Nano-Science Center & Department of Chemistry

2. University of Copenhagen

3. 2100 København Ø

4. Denmark

5. Chemical Sciences Division

6. Lawrence Berkeley National Laboratory

7. Berkeley

8. USA

9. Department of Nuclear Engineering

Abstract

Coumarin appended DO3A complexes of Cm(iii), Eu(iii), and Tb(iii) show that more than ionic radius determines the coordination chemistry of the f-elements.

Funder

Knud Højgaards Fond

Oticon Fonden

Lundbeckfonden

Villum Fonden

Carlsbergfondet

Københavns Universitet

U.S. Department of Energy

Office of Science

Basic Energy Sciences

Lawrence Berkeley National Laboratory

Publisher