Interplay between conformational and solvent effects in UV-visible absorption spectra: curcumin tautomers as a case study

Author:

Puglisi Alessandra123ORCID,Giovannini Tommaso123ORCID,Antonov Liudmil4567ORCID,Cappelli Chiara123ORCID

Affiliation:

1. Scuola Normale Superiore

2. 56126 Pisa

3. Italy

4. Bulgarian Academy of Sciences

5. Institute of Organic Chemistry with Centre of Phytochemistry

6. Sofia 1113

7. Bulgaria

Abstract

We present a combined theoretical and experimental study on the UV-vis spectra of enol–keto (EK) and keto–keto (KK) tautomeric forms of curcumin dissolved in aqueous solution.

Funder

H2020 Marie Skłodowska-Curie Actions

European Cooperation in Science and Technology

Bulgarian National Science Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference99 articles.

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2. Tautomerism: Methods and Theories , ed. L. Antonov , Wiley-VCH , Weinheim, Germany , 2013

3. The effect of the water on the curcumin tautomerism: A quantitative approach

4. Tautomerism: Concepts and Applications in Science and Technologys , ed. L. Antonov , Wiley-VCH , Weinheim, Germany , 2016

5. Tautomerism of 2-hydroxynaphthaldehyde Schiff bases †

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