Photochemistry of pyruvic acid is governed by photo-induced intermolecular electron transfer through hydrogen bonds-Reference-Cited by-同舟云学术

Photochemistry of pyruvic acid is governed by photo-induced intermolecular electron transfer through hydrogen bonds

Published:2022 Issue:40 Volume:13 Page:11849-11855
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Lewis Jennifer S.¹,Gaunt Adam P.¹,Comment Arnaud¹²^ORCID

Affiliation:

1. Cancer Research UK Cambridge Institute, University of Cambridge, Robinson Way, Cambridge, CB2 0RE, UK

2. General Electric Healthcare, Pollards Wood, Nightingales Lane, Chalfont St Giles, HP8 4SP, UK

Abstract

When supercooled pyruvic acid is photo-irradiated, a radical detectable by ESR forms following the transfer of an electron from a molecule in its keto form to a molecule in its hydrated form. The latter subsequently degrades to CO2 and acetic acid.

Funder

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC03038A

Reference42 articles.

1. Photoreduction of Pyruvic Acid by Isopropyl Alcohol and t-Butyl Alcohol. A Kinetic Study1

2. Negative production of acetoin in the photochemistry of aqueous pyruvic acid

3. Aqueous Photochemistry of 2-Oxocarboxylic Acids: Evidence, Mechanisms, and Atmospheric Impact

4. Photoinduced Oligomerization of Aqueous Pyruvic Acid

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