Magnesium cofactor produces unpaired electrons confined by triplet nucleotide loops in a full-turn DNA fragment
Author:
Affiliation:
1. Centre for Interdisciplinary Computational and Dynamical Analysis
2. University of Manchester
3. Manchester
4. UK
5. St. Petersburg State University
Abstract
The B-DNA curvature arising from pairing between nucleotides of the two curved complementary DNA strands affects the oxidation number of magnesium cofactor.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA18673D
Reference41 articles.
1. Critical Role of Magnesium Ions in DNA Polymerase β's Closing and Active Site Assembly
2. A. A. Tulub , in Metal Ions in Biology and Medicine, ed. I. Maymard, 2002, vol. 7, pp. 146–152
3. A. A. Tulub , Spintronics of nucleotides, Sci. Publ., 2010
4. Molecular dynamics DFT:B3LYP study of guanosinetriphosphate conversion into guanosinemonophosphate upon Mg2+ chelation of ? and ? phosphate oxygens of the triphosphate tail
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