Guest selectivity of [Ni2] supramolecular helicates

Author:

Imperato Manuel123ORCID,Nicolini Alessio1ORCID,Ribas-Ariño Jordi4ORCID,Antkowiak Michał35ORCID,Roubeau Olivier6ORCID,Cornia Andrea1ORCID,Novikov Valentin37ORCID,Barrios Leoní A.37ORCID,Aromí Guillem37ORCID

Affiliation:

1. Dipartimento di Scienze Chimiche e Geologiche e UdR INSTM, Università degli Studi di Modena e Reggio Emilia, via G. Campi 103, 41125 Modena, Italy

2. Dipartimento di Scienze Fisiche, Informatiche e Matematiche, Università degli Studi di Modena e Reggio Emilia, via G. Campi 213/A, 41125 Modena, Italy

3. Departament de Química Inorgànica i Orgànica, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain

4. Departament de Química Física, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain

5. Faculty of Physics, Adam Mickiewicz University, ul. Uniwersytetu Poznańskiego 2, 61-614 Poznań, Poland

6. Instituto de Nanociencia y Materiales de Aragón (INMA), CSIC and Universidad de Zaragoza, Plaza San Francisco s/n, 50009, Zaragoza, Spain

7. Institute of Nanoscience and Nanotechnology of the University of Barcelona (IN2UB), Barcelona, Spain

Abstract

A triple stranded [Ni(ii)2] coordination helicate acts as the host of a Cl or a Br ion in the solid state and in solution, with a selective preference for the former, as shown by paramagnetic 1H NMR, mass spectrometry and DFT calculations.

Funder

Ministerio de Ciencia, Innovación y Universidades

Generalitat de Catalunya

Institució Catalana de Recerca i Estudis Avançats

Publisher

Royal Society of Chemistry (RSC)

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