Conformational behaviour, photochemistry and flash vacuum pyrolysis of a 2-(1H-tetrazol-1-yl)thiophene

Author:

Soares Maria I. L.12345ORCID,Nunes Cláudio M.12345ORCID,Gomes Clara S. B.67895ORCID,Pinho e Melo Teresa M. V. D.12345ORCID,Fausto Rui12345ORCID

Affiliation:

1. CQC

2. Department of Chemistry

3. University of Coimbra

4. 3004-535 Coimbra

5. Portugal

6. Centro de Química Estrutural

7. Instituto Superior Técnico

8. Universidade de Lisboa

9. 1049-001 Lisboa

Abstract

The conformational and photochemical behaviour of a 2-(1H-tetrazol-1-yl)thiophene was studied using low-temperature matrix isolation infrared spectroscopy and theoretical calculations. FVP of 2-(1H-tetrazol-1-yl)thiophene afforded new thieno-fused heterocycles.

Funder

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference50 articles.

1. V. A. Ostrovskii , G. I.Koldobskii and R. E.Trifonov , in Comprehensive Heterocyclic Chemistry III , ed. A. R. Katritzky , C. A. Ramsden , E. F. V. Scriven , R. J. K. Taylor and V. V. Zhdankin , Elsevier , 2008 , ch. 6.07, vol. 6, pp. 257–423

2. Ring Transformations in Tetrazole Chemistry

3. RECENT DEVELOPMENTS IN TETRAZOLE CHEMISTRY. A REVIEW

4. The thermal decomposition of tetrazoles

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