Observation of proton-transfer-coupled spin transition by single-crystal neutron-diffraction measurement-Reference-Cited by-同舟云学术

Observation of proton-transfer-coupled spin transition by single-crystal neutron-diffraction measurement

Published:2023 Issue:17 Volume:25 Page:12394-12400
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Nakanishi Takumi¹,Hori Yuta²^ORCID,Shigeta Yasuteru²^ORCID,Sato Hiroyasu³,Wu Shu-Qi¹,Kiyanagi Ryoji⁴,Munakata Koji⁵,Ohhara Takashi⁴,Sato Osamu¹^ORCID

Affiliation:

1. Institute for Materials Chemistry and Engineering & IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan

2. Center for Computational Sciences, University of Tsukuba, Tsukuba 305-8577, Japan

3. Rigaku Corporation, 3-9-12 Matsubaracho, Akishima, Tokyo 196-8666, Japan

4. J-PARC Center, Japan Atomic Energy Agency, Tokai, Ibaraki 319-1195, Japan

5. Neutron Science and Technology Center, Comprehensive Research Organization for Science and Society, Tokai, Ibaraki 319-1106, Japan

Abstract

New iron(ii) complex exhibiting the proton transfer coupled spin transition and easy single crystal formation was developed. The change of nuclear position with the spin transition was successfully detected by the neutron diffraction measurement.

Funder

Japan Society for the Promotion of Science

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D3CP00527E

Reference51 articles.

1. Redox-coupled proton transfer mechanism in nitrite reductase revealed by femtosecond crystallography

2. The role of proton coupled electron transfer in water oxidation

3. Proton-Coupled Electron Transfer in Photoredox Catalytic Reactions

4. Proton transfer reactions and hydrogen-bond networks in protein environments

5. Proton-Coupled Electron Transfer Guidelines, Fair and Square

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