Catalyst-controlled regiodivergent ring-opening C(sp3)–Si bond-forming reactions of 2-arylaziridines with silylborane enabled by synergistic palladium/copper dual catalysis-Reference-Cited by-同舟云学术

Catalyst-controlled regiodivergent ring-opening C(sp3)–Si bond-forming reactions of 2-arylaziridines with silylborane enabled by synergistic palladium/copper dual catalysis

Published:2019 Issue:37 Volume:10 Page:8642-8647
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Takeda Youhei¹²³⁴⁵^ORCID,Shibuta Kaoru¹²³⁴⁵,Aoki Shohei¹²³⁴⁵,Tohnai Norimitsu⁶²³⁴⁵^ORCID,Minakata Satoshi¹²³⁴⁵^ORCID

Affiliation:

1. Department of Applied Chemistry

2. Graduate School of Engineering

3. Osaka University

4. Osaka 565-0871

5. Japan

6. Department of Material and Life Science

Abstract

A Pd/Cu catalyst-controlled regiodivergent and stereospecific ring-opening C(sp³)–Si cross-coupling of 2-arylaziridines with silylborane has been developed and a new tandem reaction to give another regioisomer of silylamine has been discovered.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC02507C

Reference52 articles.

1. M. A. Brook , Silicon in Organic, Organometallic, and Polymer Chemistry , Wiley-Interscience , New York , 2000

2. N. Anner and J.Weis , Organosilicon Chemistry V , Wiley-VCH Verlag GmbH , Weinheim , 2003

3. Nucleophilic catalysis of organosilicon substitution reactions

4. Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction

5. Palladium-Catalyzed Cross-Coupling of Monochlorosilanes and Grignard Reagents

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