The structures of ring-expanded NHC supported copper(i) triphenylstannyls and their phenyl transfer reactivity towards heterocumulenes-Reference-Cited by-同舟云学术

The structures of ring-expanded NHC supported copper(i) triphenylstannyls and their phenyl transfer reactivity towards heterocumulenes

Published:2022 Issue:3 Volume:51 Page:831-835
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Charman Rex S. C.¹^ORCID,Mahon Mary F.¹,Lowe John P.¹,Liptrot David J.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Bath. Claverton Down, Bath, BA2 7AY UK

Abstract

A copper(i) stannyl supported by a ring-expanded N-heterocyclic carbene has been synthesised and its reactivity towards heterocumulenes has been investigated.

Funder

Royal Society

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT03109K

Reference32 articles.

1. Recent applications of Stille reaction in total synthesis of natural products: An update

2. Observation of a Direct SnLi Bond; The Crystal and Molecular Structure of Monomeric[Ph3SnLi· PMDETA] and the Detection of119, 117Sn7Li NMR Coupling in Solution

3. Synthesis and structure of crystalline [K{Sn(CH2But)3}(η-C6H5Me)3] and the first NMR spectral observation of119Sn–39K coupling

4. Reactions of Phenyllithium with the Stannylene Ar*SnPh (Ar* = C6H3-2,6-Trip2; Trip = C6H2-2,4,6-Pri3) and the Synthesis of the Distannylstannylene Sn(SnPh2Ar*)2: Contrasting Behavior in Methyl and Phenyl Derivatives

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