Enantioselective synthesis of chiral heterocyclic biaryls via asymmetric Suzuki–Miyaura cross-coupling of 3-bromopyridine derivatives-Reference-Cited by-同舟云学术

Enantioselective synthesis of chiral heterocyclic biaryls via asymmetric Suzuki–Miyaura cross-coupling of 3-bromopyridine derivatives

Published:2019 Issue:9 Volume:17 Page:2351-2355
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Xia Wang¹²³⁴⁵,Zhang Zhen-Wei⁶⁷⁸⁹¹⁰,Li Yongsu¹²³⁴⁵,Jiang Xiaoding¹²³⁴⁵,Liang Hao¹²³⁴⁵,Zhang Yaqi¹²³⁴⁵,Cao Rihui¹²³⁴⁵,Qiu Liqin¹²³⁴⁵^ORCID

Affiliation:

1. School of Chemistry

2. The Key Laboratory of Low-carbon Chemistry & Energy Conservation of Guangdong Province

3. Guangdong Key Lab of Chiral Molecules and Drug Discovery

4. South China Sea Bio-Resource Exploitation and Utilization Collaborative Innovation Center

5. Sun Yat-Sen University

6. College of Pharmacy

7. Guangxi Zhuang-Yao Medicine Center of Engineering and Technology

8. Guangxi University of Chinese Medicine

9. Nanning

10. People's Republic of China

Abstract

A series of chiral heterocyclic biaryls with a pyridyl moiety were prepared in moderate to good yields with up to 92% ee via asymmetric Suzuki–Miyaura coupling.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Guangdong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/OB/C8OB03048K

Reference43 articles.

1. Atroposelective Synthesis of Axially Chiral Biaryl Compounds

2. Total synthesis of chiral biaryl natural products by asymmetric biaryl coupling

3. Atroposelective Total Synthesis of Axially Chiral Biaryl Natural Products

4. Modified BINOL Ligands in Asymmetric Catalysis

5. The Asymmetric Suzuki Coupling Route to Axially Chiral Biaryls

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