The syntheses, crystal structures, electrochemical and magnetic properties of tri-nuclear cyanide-bridged complexes [cis-MII(bpy)2(CN)2]2MnIII(salcy) (PF6) (M = Fe, Ru, Os)-Reference-Cited by-同舟云学术

The syntheses, crystal structures, electrochemical and magnetic properties of tri-nuclear cyanide-bridged complexes [cis-MII(bpy)2(CN)2]2MnIII(salcy) (PF6) (M = Fe, Ru, Os)

Published:2019 Issue:7 Volume:43 Page:3162-3168
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Liu Ming¹²³⁴⁵,Hu Jianmei¹²³⁴⁵,Yu Meng¹²³⁴⁵,Fan Weiwei¹²³⁴⁵,Ding Wenwen¹²³⁴⁵,Wang Yong¹²³⁴⁵^ORCID

Affiliation:

1. Hubei Key Laboratory of Drug Synthesis and Optimization

2. Medical Innovation Research Institute

3. Jingchu University of Technology

4. Jingmen

5. P. R. China

Abstract

Three cyanide-bridged heteronuclear complexes, [cis-M(bpy)₂(CN)₂]₂Mn(salcy) (PF₆) (M = Fe, 1; M = Ru, 2; M = Os, 3; bis(salicylideneiminato) dianion) were synthesized and fully characterized. Complexes 1 and 2 show low temperature antiferromagnetic order.

Funder

Natural Science Foundation of Hubei Province

Hubei Provincial Department of Education

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C8NJ04142C

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