Structure–reactivity relations in Cu/ZrO2 catalysed glycerol dehydration to acetol in continuous flow

Author:

Mazarío Jaime1ORCID,Jampaiah Deshetti2ORCID,Concepción Patricia1ORCID,Villasante-Iturria Pablo1,Wilson Karen3ORCID,Lee Adam3ORCID,Domine Marcelo E.1ORCID

Affiliation:

1. Instituto de Tecnología Química (UPV – CSIC), Universitat Politècnica de Valéncia, Consejo Superior de Investigaciones Científicas, Avda. Los Naranjos S/N, 46022, Valencia, Spain

2. School of Science, RMIT University, Melbourne, VIC3000, Australia

3. Centre for Catalysis and Clean Energy, School of Environment and Science, Griffith University, Gold Coast, QLD 4222, Australia

Abstract

Selective dehydration of glycerol to acetol was successfully catalysed by Cu/m-ZrO2 with monoclinic zirconia preferentially stabilising the more active Cu(i) species.

Funder

Australian Research Council

Ministerio de Economía y Competitividad

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Reference70 articles.

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5. Advanced Biotechnology: Metabolically Engineered Cells for the Bio-Based Production of Chemicals and Fuels, Materials, and Health-Care Products

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