Homolytic cleavage of Lawesson's reagent: N-heterocyclic carbene complexes of ArPS2 (Ar = 4-CH3O-C6H4)-Reference-Cited by-同舟云学术

Homolytic cleavage of Lawesson's reagent: N-heterocyclic carbene complexes of ArPS2 (Ar = 4-CH3O-C6H4)

Published:2018 Issue:18 Volume:47 Page:6299-6303
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Soleimani Ebrahim¹²³⁴⁵^ORCID,Robertson Katherine N.⁵¹⁶⁷⁸^ORCID,Pye Cory C.⁵¹⁶⁷⁸^ORCID,Clyburne Jason A. C.⁵¹⁶⁷⁸^ORCID

Affiliation:

1. Department of Chemistry

2. Razi University

3. Kermanshah 67149-67346

4. Iran

5. The Atlantic Centre for Green Chemistry

6. Saint Mary's University

7. Halifax

8. Canada

Abstract

Lawesson's reagent has been shown to react with the N-heterocyclic carbenes [1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes) and 1,3-bis(2,6-diisopropylphenyl)imidazolidin-2-ylidene (SIPr)] to give adducts of the general form NHC·P(S)₂-C₆H₄OCH₃.

Funder

Natural Sciences and Engineering Research Council of Canada

Nova Scotia Research Innovation Trust

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT00457A

Reference23 articles.

1. Applications of Lawesson’s reagent in the synthesis of naturally occurring steroids and terpenoids

2. Applications of Lawesson’s Reagent in Organic and Organometallic Syntheses

3. Use of Lawesson's Reagent in Organic Syntheses

4. Computational Mechanistic Study of Thionation of Carbonyl Compounds with Lawesson’s Reagent

5. Pivotal Neighboring-Group Participation in Substitution versus Elimination Reactions - Computational Evidence for Ion Pairs in the Thionation of Alcohols with Lawesson's Reagent

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