Thermodynamic description of Tc(iv) solubility and carbonate complexation in alkaline NaHCO3–Na2CO3–NaCl systems
Author:
Affiliation:
1. Institute for Nuclear Waste Disposal
2. Karlsruhe Institute of Technology
3. 76021 Karlsruhe
4. Germany
5. Los Alamos National Laboratory
Abstract
A comprehensive thermodynamic model is derived for the system Tc4+–Na+–Cl−–OH−–HCO3−–CO32−–H2O(l) based upon solubility experiments in alkaline carbonate solutions, advanced spectroscopic techniques and DFT calculations.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT00250A
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