Diguanidinocalix[4]arenes as effective and selective catalysts of the cleavage of diribonucleoside monophosphates-Reference-Cited by-同舟云学术

Diguanidinocalix[4]arenes as effective and selective catalysts of the cleavage of diribonucleoside monophosphates

Published:2014 Issue:65 Volume:4 Page:34412-34416
ISSN:2046-2069
Container-title:RSC Adv.
language:en
Short-container-title:RSC Adv.

Author:

Salvio Riccardo¹²³,Cacciapaglia Roberta¹²³,Mandolini Luigi¹²³,Sansone Francesco⁴⁵⁶,Casnati Alessandro⁴⁵⁶^ORCID

Affiliation:

1. Dipartimento di Chimica and IMC – CNR Sezione Meccanismi di Reazione

2. Università La Sapienza

3. 00185 Roma, Italy

4. Dipartimento di Chimica

5. Università degli Studi di Parma

6. 43124 Parma, Italy

Abstract

Upper rim diguanidino-cone-calix[4]arenes catalyze the hydrolytic cleavage of diribonucleoside monophosphates in aqueous DMSO with good substrate selectivity and rate accelerations approaching 10⁵-fold in the most favourable substrate-catalyst combinations.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/RA/C4RA05751A

Reference46 articles.

1. Degrees of Difficulty of Water-Consuming Reactions in the Absence of Enzymes

2. Dinuclear metallo-phosphodiesterase models: application of calix[4]arenes as molecular scaffolds

3. Synthetic metallonucleases for RNA cleavage

4. Di- and Trinuclear Zn2+ Complexes of Calix[4]arene Based Ligands as Catalysts of Acyl and Phosphoryl Transfer Reactions

5. Catalysis of Diribonucleoside Monophosphate Cleavage by Water Soluble Copper(II) Complexes of Calix[4]arene Based Nitrogen Ligands

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