Proton-coupled electron transfer in the electrocatalysis of CO2 reduction: prediction of sequential vs. concerted pathways using DFT-Reference-Cited by-同舟云学术

Proton-coupled electron transfer in the electrocatalysis of CO2 reduction: prediction of sequential vs. concerted pathways using DFT

Published:2017 Issue:1 Volume:8 Page:458-465
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Göttle Adrien J.¹²³⁴,Koper Marc T. M.¹²³⁴

Affiliation:

1. Leiden Institute of Chemistry

2. Leiden University

3. 2300 RA Leiden

4. The Netherlands

Abstract

We provide a complete and computationally detailed picture of the mechanism of the initial stages of the electrocatalytic reduction of CO₂ in water catalysed by cobalt porphyrin complexes.

Funder

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C6SC02984A

Reference57 articles.

1. Catalysis for the Valorization of Exhaust Carbon: from CO2 to Chemicals, Materials, and Fuels. Technological Use of CO2

2. International Energy Agency , Key World Energy Stat., 2015, vol. 2015

3. The geographical distribution of fossil fuels unused when limiting global warming to 2 °C

4. A review on the electrochemical reduction of CO2 in fuel cells, metal electrodes and molecular catalysts

5. Cobalt−Porphyrin Catalyzed Electrochemical Reduction of Carbon Dioxide in Water. 1. A Density Functional Study of Intermediates

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