Two pillared-layer metal–organic frameworks based on the pinwheel trinuclear carboxylate-clusters of Zn(<scp>ii</scp>) and Co(<scp>ii</scp>): synthesis, crystal structures, magnetic study, and Lewis acid catalysis-Reference-Cited by-同舟云学术

Two pillared-layer metal–organic frameworks based on the pinwheel trinuclear carboxylate-clusters of Zn(ii) and Co(ii): synthesis, crystal structures, magnetic study, and Lewis acid catalysis

Published:2023 Issue:5 Volume:52 Page:1449-1460
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Das Moyna¹,Jaswal Vishakha¹,Bhambri Himanshi²,Das Prasenjit³,Maity Suvendu⁴,Ghosh Prasanta⁴^ORCID,Mandal Sanjay K.²^ORCID,Sarkar Madhushree¹^ORCID

Affiliation:

1. Department of Chemistry, Birla Institute of Technology and Science, Pilani, Pilani Campus, Rajasthan 333031, India

2. Department of Chemical Sciences, Indian Institute of Science Education and Research Mohali, Sector 81, S.A.S. Nagar, Punjab 140 306, India

3. Technische Universität Berlin, Department of Chemistry/Functional Materials, Hardenbergstr. 40, 10623 Berlin, Germany

4. Department of Chemistry, Ramakrishna Mission Residential College, Narendrapur, Kolkata-700103, India

Abstract

Zn-MOF and Co-MOF have 3D pillared-layer structure based on pinwheel trinuclear metal-carboxylate clusters. Zn-MOF is efficient catalyst for Knoevenagel condensation reaction while Co-MOF have shown magnetic properties due to the trimeric Co(ii).

Funder

Birla Institute of Technology and Science, Pilani

Council for Scientific and Industrial Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D2DT04106E

Reference74 articles.

1. Applications of water stable metal–organic frameworks

2. Metal Organic Framework Catalysis: Quo vadis?

3. Metal–organic framework materials as catalysts

4. Metal–organic frameworks with Lewis acidity: synthesis, characterization, and catalytic applications

5. Synthesis and catalytic applications of metal–organic frameworks: a review on recent literature

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