Quaternary ammonium salts of phenylglyoxylic acid as photobase generators for thiol-promoted epoxide photopolymerization

Author:

Salmi H.123,Allonas X.123,Ley C.123,Defoin A.123,Ak A.123

Affiliation:

1. Laboratory of Macromolecular Photochemistry and Engineering

2. University of Haute Alsace

3. 68093 Mulhouse, France

Abstract

A novel series of photobase generators (PBGs), which are quaternary ammonium salts of phenylglyoxylic acid (PA) having the ability to generate strong bases such as 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU), 1,5-diazabicyclo[4.3.0]non-5-ene (DBN) or 1,1,3,3-tetramethylguanidine (TMG), was synthesized.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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5. J. V. Crivello , K.Dietliker and G.Bradley , in Photoinitiators for Free Radical Cationic & Anionic Photopolymerisation 2nd Edition: Chemistry & Technology of UV & EB Formulation for Coatings, Inks & Paints , Wiley , Chichester , 1998 , vol. 3

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