Highly regio- and stereoselective synthesis of cyclic carbonates from biomass-derived polyolsviaorganocatalytic cascade reaction

Author:

Zhou Hui1234ORCID,Zhang Hui1234,Mu Sen1234,Zhang Wen-Zhen1234ORCID,Ren Wei-Min1234ORCID,Lu Xiao-Bing1234

Affiliation:

1. State Key Laboratory of Fine Chemicals

2. Dalian University of Technology

3. Dalian 116024

4. China

Abstract

Dual Lewis base–CO2adduct/MTBD organocatalytic system was developed for the cascade reaction of CO2, propargylic alcohol, and polyhydroxy compounds to afford various functionalized cyclic carbonates in high regio- and stereoselectivity.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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