Copolymerisation of 1-alkenes with bulky oxygen-containing olefins for dual-stage functionalisation of polyolefins

Author:

Takeuchi Daisuke12345ORCID,Nakamura Makoto67895,Osakada Kohtaro67895ORCID

Affiliation:

1. Department of Frontier Materials Chemistry

2. Faculty of Science and Technology

3. Hirosaki University

4. Aomori 036-8561

5. Japan

6. Laboratory for Chemistry and Life Science

7. Institute of Innovative Research

8. Tokyo Institute of Technology

9. Yokohama 226-8503

Abstract

Pd–Diimine complexes catalyse the copolymerisation of 1-alkenes with olefins having a bulky oxygen-containing substituents, such as cyclic acetal or bicycloorthoester groups, affording the copolymers containing the comonomer unit up to 34%.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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