Photocatalytic, modular difunctionalization of alkenes enabled by ligand-to-metal charge transfer and radical ligand transfer-Reference-Cited by-同舟云学术

Photocatalytic, modular difunctionalization of alkenes enabled by ligand-to-metal charge transfer and radical ligand transfer

Published:2024 Issue:1 Volume:15 Page:124-133
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Bian Kang-Jie¹,Nemoto David¹,Chen Xiao-Wei¹^ORCID,Kao Shih-Chieh¹,Hooson James¹,West Julian G.¹^ORCID

Affiliation:

1. Department of Chemistry, Rice University, 6100 Main St MS 602, Houston, TX 77005, USA

Abstract

Simple iron salts are able to photocatalyze the diazidation, dichlorination, and fluorochlorination of alkenes via the merger of ligand-to-metal charge transfer (LMCT) and either radical ligand transfer (RLT) or fluorine atom transfer (FAT).

Funder

Welch Foundation

Research Corporation for Science Advancement

Cancer Prevention and Research Institute of Texas

National Institute of General Medical Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC05231A

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