Single-atom alloy structure and unique bonding properties of Au104Ag40(PET)60 nanoclusters-Reference-Cited by-同舟云学术

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Single-atom alloy structure and unique bonding properties of Au₁₀₄Ag₄₀(PET)₆₀ nanoclusters

Published:2024 Issue:34 Volume:16 Page:16140-16147
ISSN:2040-3364
Container-title:Nanoscale
language:en
Short-container-title:Nanoscale

Author:

Morris David¹^ORCID,Du Xiangsha²,Jin Rongchao²^ORCID,Zhang Peng¹^ORCID

Affiliation:

1. Department of Chemistry, Dalhousie University, Halifax B3H 4R2, Canada

2. Department of Chemistry, Carnegie Mellon University, Pittsburgh 15213, USA

Abstract

X-ray absorption spectroscopy is utilized to study the distribution of Au and Ag within the metal core of the Au104Ag40(PET)60 nanocluster, revealing a Ag single-atom alloy structure associated with unique bonding properties.

Funder

Natural Sciences and Engineering Research Council of Canada

U.S. Department of Energy

University of Saskatchewan

Canadian Institutes of Health Research

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NR/D4NR02688H

Reference36 articles.

1. Quantum sized, thiolate-protected gold nanoclusters

2. Protein-Directed Synthesis of Highly Fluorescent Gold Nanoclusters

3. Glutathione-Protected Gold Clusters Revisited: Bridging the Gap between Gold(I)−Thiolate Complexes and Thiolate-Protected Gold Nanocrystals

4. Sensitive X-ray Absorption Near Edge Structure Analysis on the Bonding Properties of Au30(SR)18 Nanoclusters

5. Atomically Precise Colloidal Metal Nanoclusters and Nanoparticles: Fundamentals and Opportunities

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