Pressure and temperature dependent kinetics and the reaction mechanism of Criegee intermediates with vinyl alcohol: a theoretical study-Reference-Cited by-同舟云学术

Pressure and temperature dependent kinetics and the reaction mechanism of Criegee intermediates with vinyl alcohol: a theoretical study

Published:2024 Issue:12 Volume:26 Page:9524-9533
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Sun Cuihong¹^ORCID,Xu Baoen¹^ORCID,Zeng Yanli²^ORCID

Affiliation:

1. Shijiazhuang Key Laboratory of Low Carbon Energy Materials, Technology Innovation Center of HeBei for Heterocyclic Compound, College of Chemical Engineering, Shijiazhuang University, Shijiazhuang 050035, P. R. China

2. College of Chemistry and Materials Science, Hebei Normal University, Shijiazhuang 050024, P.R. China

Abstract

The 1,4-insertion is the main channel for the CH2OO + syn-VA reaction, while the cycloaddition is more competitive in the CH2OO + anti-VA reaction. The dissociation products involving OH radicals are formed at higher temperature and lower pressure.

Funder

Natural Science Foundation of Hebei Province

Department of Education of Hebei Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D3CP06115A

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5. Direct observation of OH formation from stabilised Criegee intermediates