Metal-free synthesis of poly(trimethylene carbonate) by efficient valorization of carbon dioxide-Reference-Cited by-同舟云学术

Metal-free synthesis of poly(trimethylene carbonate) by efficient valorization of carbon dioxide

Published:2019 Issue:3 Volume:21 Page:472-477
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Huang Jin¹²³⁴⁵^ORCID,De Winter Julien⁶⁴⁵^ORCID,Dove Andrew P.⁷⁸⁹¹⁰^ORCID,Coulembier Olivier¹²³⁴⁵^ORCID

Affiliation:

1. Laboratory of Polymeric and Composite Materials (LPCM)

2. Centre of Innovation and Research in Materials and Polymers (CIRMAP)

3. University of Mons

4. Mons

5. Belgium

6. Organic Synthesis and Mass Spectrometry Laboratory (S2MOS) University of Mons

7. School of Chemistry

8. University of Birmingham

9. Birmingham

10. UK

Abstract

The green I₂/TBD catalytic complex is demonstrated competitive to metal-based systems in the preparation of PTMC through a two-step process mechanism.

Funder

H2020 Marie Skłodowska-Curie Actions

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/GC/C8GC03607A

Reference56 articles.

1. Organic synthesis using carbon dioxide as phosgene-free carbonyl reagent

2. Direct Cyclic Carbonate Synthesis from CO2 and Diol over Carboxylation/Hydration Cascade Catalyst of CeO2 with 2-Cyanopyridine

3. A facile catalytic synthesis of trimethylene carbonate from trimethylene oxide and carbon dioxide

4. A Powerful Aluminum Catalyst for the Synthesis of Highly Functional Organic Carbonates

5. Synthesis of 6-membered cyclic carbonates from 1,3-diols and low CO2 pressure: a novel mild strategy to replace phosgene reagents

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