Asymmetric synthesis of γ-chiral borylalkanes via sequential reduction/hydroboration using a single copper catalyst-Reference-Cited by-同舟云学术

Asymmetric synthesis of γ-chiral borylalkanes via sequential reduction/hydroboration using a single copper catalyst

Published:2020 Issue:33 Volume:11 Page:8961-8965
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Han Jung Tae¹²³⁴⁵^ORCID,Lee Jin Yong¹²³⁴⁵^ORCID,Yun Jaesook¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Institute of Basic Science

3. Sungkyunkwan University

4. Suwon 16419

5. Korea

Abstract

Copper-catalyzed reductive hydroboration of γ,γ-disubstituted allylic substrates enables preparation of γ-chiral alkylboron compounds in a one-pot cascade manner.

Funder

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC03759A

Reference74 articles.

1. Enantioselective Heck Arylations of Acyclic Alkenyl Alcohols Using a Redox-Relay Strategy

2. Enantioselective construction of remote quaternary stereocentres

3. Enantioselective γ-Alkylation of α,β-Unsaturated Malonates and Ketoesters by a Sequential Ir-Catalyzed Asymmetric Allylic Alkylation/Cope Rearrangement

4. Synthesis of Amides with Remote Stereocenters by Catalytic Asymmetric γ-Alkynylation of α,β-Unsaturated Amides

5. Enantioselective construction of remote tertiary carbon–fluorine bonds

Cited by 5 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Enantioselective synthesis of γ-chiral amides via copper-catalyzed reductive relay hydroaminocarbonylation;Nature Communications;2024-08-07

2. Enantio- and Regioselective Dihydroboration of Enals;ACS Catalysis;2024-02-28

3. Hydroboration of C–C π-Bonds;Reference Module in Chemistry, Molecular Sciences and Chemical Engineering;2023

4. Copper-Catalyzed Asymmetric Conjugate Addition of Alkene-Derived Nucleophiles to Alkenyl-Substituted Heteroarenes;ACS Catalysis;2022-07-22

5. Copper-catalyzed borylative aminomethylation of C–C double and triple bonds with N,O-acetal;Chemical Communications;2021