A synthesis-enabled relative configurational assignment of the C31–C46 region of hemicalide-Reference-Cited by-同舟云学术

A synthesis-enabled relative configurational assignment of the C31–C46 region of hemicalide

Published:2022 Issue:38 Volume:58 Page:5729-5732
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Stockdale Tegan P.¹,Lam Nelson Y. S.¹^ORCID,Paterson Ian¹^ORCID

Affiliation:

1. Yusuf Hamied Department of Chemistry, Lensfield Road, Cambridge, CB2 1EW, UK

Abstract

Detailed NMR spectroscopic comparisons with a series of truncate candidates enables the structural elucidation of the C31–C46 region of hemicalide, reducing the number of possible diastereomers from over one million down to eight.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC01802K

Reference27 articles.

1. Relative Stereochemical Determination and Synthesis of the C1−C17 Fragment of a New Natural Polyketide

2. Assigning Stereochemistry to Single Diastereoisomers by GIAO NMR Calculation: The DP4 Probability

3. Toward the stereochemical assignment and synthesis of hemicalide: DP4f GIAO-NMR analysis and synthesis of a reassigned C16–C28 subunit

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