Broadening the catalytic region from the cavity to windows by M<sub>6</sub>L<sub>12</sub> nanospheres in cyclizations-Reference-Cited by-同舟云学术

Broadening the catalytic region from the cavity to windows by M₆L₁₂ nanospheres in cyclizations

Published:2023 Issue:42 Volume:14 Page:11699-11707
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Xu Meiling¹,Sun Bin²,Poole David A.²^ORCID,Bobylev Eduard O.²,Jing Xu¹^ORCID,Wu Jinguo¹,He Cheng¹^ORCID,Duan Chunying¹^ORCID,Reek Joost N. H.²^ORCID

Affiliation:

1. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116024, P. R. China

2. Homogeneous, Supramolecular and Bio-Inspired Catalysis, Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, Amsterdam 1098 XH, The Netherlands

Abstract

M6L12 nanospheres, with isolated gold sites fixed on the windows, were utilized as an example to prove that the cage windows present a confinement effect for substrate pre-organization and transition state stabilization leading to high rates.

Funder

National Natural Science Foundation of China

Universiteit van Amsterdam

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC02998K

Reference53 articles.

1. Metal–Organic Polyhedron Capped with Cucurbit[8]uril Delivers Doxorubicin to Cancer Cells

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5. Recent Developments in the Preparation and Chemistry of Metallacycles and Metallacages via Coordination

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