A rational design strategy of radical-type mechanophores with thermal tolerance-Reference-Cited by-同舟云学术

A rational design strategy of radical-type mechanophores with thermal tolerance

Published:2023 Issue:33 Volume:14 Page:8792-8797
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Lu Yi¹,Sugita Hajime¹²,Mikami Koichiro²^ORCID,Aoki Daisuke¹^ORCID,Otsuka Hideyuki¹³^ORCID

Affiliation:

1. Department of Chemical Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8550, Japan

2. Sagami Chemical Research Institute, 2743-1 Hayakawa, Ayase, Kanagawa 252-1193, Japan

3. Living Systems Materialogy (LiSM) Research Group, International Research Frontiers Initiative (IRFI), Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8501, Japan

Abstract

Radical-type mechanophores (RMs) are attractive molecules that undergo homolytic scission of their central C–C bond to afford radical species upon exposure to heat or mechanical stimuli.

Funder

Core Research for Evolutional Science and Technology

Japan Science and Technology Agency

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC02991C

Reference69 articles.

1. Force-induced activation of covalent bonds in mechanoresponsive polymeric materials

2. Heterolytic Bond Cleavage in a Scissile Triarylmethane Mechanophore

3. Stimuli-Responsive Covalent Adaptable Hydrogels Based on Homolytic Bond Dissociation and Chain Transfer Reactions

4. Mechanoresponsive self-growing hydrogels inspired by muscle training

5. Mechanically induced chemiluminescence from polymers incorporating a 1,2-dioxetane unit in the main chain

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