The unusual hydridicity of a cobalt bound Si–H moiety-Reference-Cited by-同舟云学术

The unusual hydridicity of a cobalt bound Si–H moiety

Published:2016 Issue:60 Volume:52 Page:9367-9370
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kim Jin¹²³⁴,Kim Yujeong⁵⁶⁷⁴⁸,Sinha Indranil¹²³⁴⁹,Park Koeun¹²³⁴,Kim Sun Hee⁵⁶⁷⁴⁸,Lee Yunho¹²³⁴⁹

Affiliation:

1. Department of Chemistry

2. Korea Advanced Institute of Science and Technology

3. Daejeon 34141

4. Republic of Korea

5. Western Seoul Centre

6. Korea Basic Science Institute

7. Seoul 03759

8. Department of Chemistry and Nano Science

9. Centre for Catalytic Hydrocarbon Functionalizations

Abstract

A paramagnetic cobalt–SiH intermediate possessing the Co–(η¹-H–Si) moiety shows unusual Si–H bond activation studied by ENDOR, XRD and DFT.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC03983A

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4. A Review of Recent Progress in Catalyzed Homogeneous Hydrosilation (Hydrosilylation)

5. The Addition of Silicon Hydrides to Olefinic Double Bonds. Part II. The Use of Group VIII Metal Catalysts

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