Theoretical investigation of the nature of π(BB)⋯M interactions in coinage metal π-diborene complexes-Reference-Cited by-同舟云学术

Theoretical investigation of the nature of π(BB)⋯M interactions in coinage metal π-diborene complexes

Published:2021 Issue:30 Volume:45 Page:13380-13388
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Li Zhendong¹²³,Liu Yulin¹²³,Li Xiaomeng¹²³,Li Qingzhong⁴⁵³^ORCID,Li Xiaoyan¹²³^ORCID

Affiliation:

1. College of Chemistry and Material Science, Hebei Key Laboratory of Inorganic and Nano-Materials, National Demonstration Center for Experimental Chemistry, Hebei Normal University

2. Shijiazhuang

3. China

4. The Laboratory of Theoretical and Computational Chemistry, College of Chemistry & Chemical Engineering, Yantai University

5. Yantai

Abstract

π(BB)⋯M interactions are strong covalent bonds and their strengths increase in the sequence of M = Ag, Cu, and Au, for the same number of MCl. Theoretical investigation on the nature of π(BB)⋯M interactions in coinage metal π-diborene complexes is outlined here.

Funder

Natural Science Foundation of Hebei Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/NJ/D1NJ02744A

Reference64 articles.

1. Preparation and Characterization of the Binary Group 13 Azides M(N3)3 and M(N3)3⋅CH3CN (M=Ga, In, Tl), [Ga(N3)5]2−, and [M(N3)6]3− (M=In, Tl)

2. Organometallics of the Group 13 M−M Bond (M = Al, Ga, In) and the Concept of Metalloaromaticity