Halogen regulation triggers structural transformation from centrosymmetric to noncentrosymmetric switches in tin phosphate halides Sn<sub>2</sub>PO<sub>4</sub>X (X = F, Cl)-Reference-Cited by-同舟云学术

Halogen regulation triggers structural transformation from centrosymmetric to noncentrosymmetric switches in tin phosphate halides Sn₂PO₄X (X = F, Cl)

Published:2022 Issue:18 Volume:9 Page:4705-4713
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Zheng Ting¹,Wang Qiang¹,Ren JinXuan¹,Cao Liling¹^ORCID,Huang Ling¹^ORCID,Gao Daojiang¹^ORCID,Bi Jian¹,Zou Guohong²^ORCID

Affiliation:

1. College of Chemistry and Materials Science, Sichuan Normal University, Chengdu, 610066, P. R. China

2. College of Chemistry, Sichuan University, Chengdu, 610065, P. R. China

Abstract

A tin phosphate halide, centrosymmetric Sn2PO4F, was successfully transformed into noncentrosymmetric Sn2PO4Cl with excellent comprehensive performance by the substitution of F− with Cl−.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QI/D2QI01207C

Reference56 articles.

1. Design and synthesis of an ultraviolet-transparent nonlinear optical crystal Sr2Be2B2O7

2. Ultraviolet lasers

3. Molecular Structures and Second-Order Nonlinear Optical Properties of Ionic Organic Crystal Materials