Direct aerobic liquid phase epoxidation of propylene catalyzed by Mn(iii) porphyrin under mild conditions: evidence for the existence of both peroxide and Mn(iv)-oxo species from in situ characterizations-Reference-Cited by-同舟云学术

Direct aerobic liquid phase epoxidation of propylene catalyzed by Mn(iii) porphyrin under mild conditions: evidence for the existence of both peroxide and Mn(iv)-oxo species from in situ characterizations

Published:2015 Issue:38 Volume:5 Page:30014-30020
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Li Yang¹²³⁴⁵,Zhou Xiantai¹²³⁴⁵,Chen Shaoyun¹²³⁴⁵,Luo Rongchang¹²³⁴⁵,Jiang Jun¹²³⁴⁵,Liang Zhongxiu¹²³⁴⁵,Ji Hongbing¹²³⁴⁵

Affiliation:

1. School of Chemistry and Chemical Engineering

2. Key Laboratory of Low-Carbon Chemistry & Energy Conservation of Guangdong Province

3. Sun Yat-sen University

4. Guangzhou 510275

5. China

Abstract

Manganese(iii) porphyrin exhibited excellent activity for the selective oxidation of propylene. Experimental evidences that the generation of peroxide and Mn(iv) oxo species, which was well confirmed by in situ IR, in situ UV and MS.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C4RA15601C

Reference69 articles.

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