Porphyrin-containing conjugated microporous polymers with gradient asymmetric design for efficient oxygen reduction

Author:

Zheng Kunpeng1,Wang Maorong1,Wang Binbin1,Wang Meilong1,Wang Zhong2,Long Xiaojing1ORCID

Affiliation:

1. State Key Laboratory of Bio-fibers and Eco-textiles, Collaborative Innovation Center of Shandong Marine Biobased Fibers and Ecological textiles, Institute of Marine Biobased Materials, College of Materials Science and Engineering, Qingdao University, Qingdao 266071, P. R. China

2. Key Laboratory of Biofuels, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, China

Abstract

Gradient asymmetry is employed to design metal-free polymer electrocatalysts. The superior activity of the highly asymmetric PPA-BN is attributed to the abundant active sites and adequate oxygen intermediate adsorption by local charge distribution.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

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