Unusual fluorescence behaviour of a heteroleptic Cu(i) complex featuring strong electron donating groups on a diimine ligand-Reference-Cited by-同舟云学术

Unusual fluorescence behaviour of a heteroleptic Cu(i) complex featuring strong electron donating groups on a diimine ligand

Published:2022 Issue:4 Volume:46 Page:1693-1703
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Santander-Nelli Mireya¹²^ORCID,Sanhueza Luis³⁴,Navas Daniel⁵,Rossin Elena⁶⁷,Natali Mirco⁶^ORCID,Dreyse Paulina¹^ORCID

Affiliation:

1. Departamento de Química, Universidad Técnica Federico Santa María, Av. España 1680, Casilla 2390123, Valparaíso, Chile

2. Centro Integrativo de Biología y Química Aplicada (CIBQA), Universidad Bernardo O'Higgins, General Gana 1702, Santiago 8370854, Chile

3. Departamento de Ciencias Biológicas y Químicas, Facultad de Recursos Naturales, Universidad Católica de Temuco, Casilla 15-D, Temuco, Chile

4. Núcleo de Investigación en Bioproductos y Materiales Avanzados (BioMA), Universidad Católica de Temuco, Av. Rudecindo Ortega, 02950 Temuco, Chile

5. Departamento de Química, Facultad de Ciencias Naturales, Matemática y del Medio Ambiente, Universidad Tecnológica Metropolitana, Las Palmeras 3360, Ñuñoa, Santiago 7800003, Chile

6. Department of Chemical, Pharmaceutical and Agricultural Sciences (DOCPAS), University of Ferrara, Via L. Borsari 46, 44121 Ferrara, Italy

7. Department of Chemical Sciences, University of Padova, Via F. Marzolo 1, 35131, Padova, Italy

Abstract

Synthesis of a novel bulky diimine ligand and its corresponding heteroleptic Cu(i). Unusual fluorescence behavior of a novel Cu(i) complex due to a strong electron-donor diimine ligand.

Funder

Fondo Nacional de Desarrollo Científico y Tecnológico

Università degli Studi di Ferrara

Universidad Técnica Federico Santa María

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D1NJ04811B

Reference55 articles.

1. Heteroleptic diimine–diphosphine Cu(I) complexes as an alternative towards noble-metal based photosensitizers: Design strategies, photophysical properties and perspective applications